Comparative analysis of adding cotton straw and corn stover to improve the combustion performance of municipal sludge

To address issues of high water content and low calorific value during combustion of municipal sludge, we added water-absorbent, easy-to-burn agricultural waste to improve the overall combustion performance. Cotton straw or corn stover were added to the sludge and mixed at high-speed to compare their capacities for improving combustion performance. Scanning Electron Microscopy (SEM) revealed that cotton straw or corn stover attached to the surface of the municipal sludge particles after blending, while analysis of thermogravimetric curves and activation energies of the blends showed that combustion and exhaustion rates increased significantly when 40% cotton straw or corn stover were blended into the sludge. Using the quadrilateral cut-ring boiler as a prototype, the mix of sludge with cotton straw or corn stover was simulated, and FLUENT software was used to obtain the temperature and pollutant emissions of the boiler. Sludge blended with cotton straw or corn stover increased furnace temperature and reduced SO2 and NO emissions, while that with cotton straw burned at higher temperatures with lower SO2 and NO emissions. Overall, the CO content of sludge combustion was lower when blended with proportions of cotton straw or corn stover under 50%. The findings of this study lay a theoretical foundation for treatment of municipal sludge according to local conditions.

biomass + 20% sludge were lower than those from sludge combustion, NO x was reduced by about 66% and SO 2 by 80%.Further, Jingyong Liu 10 et al. (2018) concluded that 60.1% blending of sewage sludge and water hyacinth resulted in the best combustion parameters at a heating rate of 29.9˚C/min, and a maximum burnout rate of 92.4%.Jin-Ho Sung 11 et al. (2018)concluded that 70%sludge + 30% biomass, with 23% oxygen mixing rate When burning in a 30 kWth CFB, lowest temperature gap between riser and stack occurred, high enrichment of CO 2 (over 90%) with less pollutant emissions, specifically 0.91% CO and 14 ppm NO.
Given the large-scale production of urban sludge containing high moisture 12 content, low calorific value 13,14 , low level of resource utilization and low recycling of energyas, as well as that of cotton straw and corn stover (containing high cellulose and hemicellulose contents and calorific value) [15][16][17] , in Xinjiang, this study features a comparative analysis on the combustion performance of urban sludge after addition of different proportions of cotton straw or corn stover waste.Using the advantages of Computational Fluid Dynamics (CFD), such as high operability, low cost, and effective observation of the combustion process 18 , the temperature and flue gas distribution of sludge mixed with cotton straw (or corn stover) in a quadrangular cut-circle boiler were solved by Fluent software.Studies of this nature are critical in the search for new biomass fuels to replace fossil fuels in thermal power plants, and for providing theoretical support for cleaner production while synergistically promoting carbon and pollution reduction.A schematic diagram of the synergistic resource utilisation strategy for treatment of municipal sludge is shown in Fig. 1.

Materials and pre-processing
The experimental sludge was obtained from the domestic wastewater treatment plant (WWTP) ex-factory sludge with 80% water content.The wastewater treatment process of this wastewater treatment plant is activated sludge method.The effluent sludge is the sludge after dosing, disinfection and mechanical dewatering and is disinfected.The experimental mud is not dried above 60 °C.The sludge is a zoogloea and there is no bacteria treatment during the whole process.The cotton straw used in the experiment were obtained from cotton straw of long-staple cotton harvested in autumn in Xinjiang.The corn stover used in the experiment came from the corn stover of MC670 corn after harvesting in autumn in Xinjiang.Natural air drying of sludge taken from sewage treatment plant, and then subject to the use of RRH-100 crusher, take 0.075 mm sludge particles for spare.Cotton straw, and corn stover were pre-processed the same way, the same RRH-100 crusher was used to crush and 0.075 mm particles were taken for spare.

Mixing methods
An RRH-100 crusher, set at a mixing speed of 28,000 rpm, was used as the mixing device.Figure 2 shows a schematic diagram of the blending process.Sludge with a particle size of 0.075 mm was placed in a mixing unit with cotton straw (or corn stover) and stirred for 5 min.The mixing device oscillated at a uniform speed during the mixing process, which promoted the homogeneous mixing of the sludge with the cotton straw or corn stover.Table 1 shows the instrument types and models.

Microstructure analysis
Scanning electron microscopy was carried out using a German Zeiss SEM field emission scanning electron microscope GeminiSEM 300 for microstructure observation.A 10 mg substrate, with a particle size of 0.075 mm, was glued to the conductive adhesive, then 45 s gold spraying with 10 mA using a Quorum SC7620 sputter coater.Working distance is 8.5 mm.The acceleration voltage was set to 3 kV and a magnification of 2000X for morphology filming.The microstructures of sludge, cotton straw, and corn stover were observed and analysed before and after blending.

Thermogravimetric analysis
Thermogravimetric experiments were performed using a German NETZSCH TG209F1 analyser.The heating rate was 20 °C/min, starting at 25 °C and reaching 1000 °C.Throughout the experiment, the atmosphere was ambient air, with an air intake rate of 60 ml/min.The thermodynamic curves of the sludge, cotton straw, and corn stover were analysed in individually and in combinations of sludge with corn stover or cotton straw 19,20 .Table 2 shows the technical parameters of thermogravimetric analyzer.

Kinetic analysis
Activation energy is the energy required for a substance to change from its normal state to an active state; the higher the activation energy, the more difficult it is for a substance to react chemically 21 .In this experiment, the Coats-Redfern 22,23 model was used to calculate the activation energy of an inhomogeneous system under nonisothermal conditions, using Eqs. 1 and 2: (1) dα dT  where A is the prime factor; β is the rate of temperature increase, °C/min; E is the activation energy, kJ/mol; R is the ideal gas constant, 8.314 J/mol-K;T is the thermodynamic temperature, K;α is the percent conversion; m 0 is the initial mass of the sample, mg; m ∞ is the sample reaction termination mass, mg; m t is the sample mass at time t, mg; f (α) is the mechanism function; and G(α) is the kinetic model function.
Through integration of Eq. (1), we get Eq.( 3), where Using the Coats-Redfern model, the integral of Eq. ( 3) takes the logarithmic form, as expressed in Eq. ( 4): where 1/T represents the horizontal axis and ln(G(α)/2 ) represents the vertical axis.The function was linearly fit to find the activation energy, and pre-exponential factor A.

Simulation analysis
In this study, a 330 MW quadrangular tangent circle commonly used in Xinjiang is used for numerical simulation.The diameter, width, and height of the boiler were 12.80 m, 12.80 m, and 55.23 m, respectively.The operating parameters of the boiler are listed in Table 3 and the simulated combustion feed ratios are listed in Table 4.
In this study, Fluent 14.0 from Ansys software was used, which consists of 565,206 structural units, as shown in Fig. 3.The grid was refined at important locations, such as primary air nozzles and material nozzles.The modelling and computational methods considered for the validity and accuracy of the model were as follows: (3)   1.Standard modelling equations including the conservation of mass, conservation of energy, conservation of momentum, and conservation of substance concentration equations were used 24 .2. A matter transport model was combined with a discrete-phase model to simulate boiler combustion 25 .3. A simulation of turbulent gas flow in pulverised coal boilers was carried out using the standard j-e turbulence model 26 .4. Radiative heat transfer was calculated using the P-1 radiation model, because heat transfer affects combustion and particle behaviour 27 .5. The surface reaction of the fuel combustion was modelled using a finite rate/vortex dissipation model 28 .6.The NO X model primarily considered thermal NO X and fuel NO X 29,30 .

Elemental analysis and industrial analysis
The experiments were carried out according to the experimental methods in "Elemental and industrial analyses and calorific values" and the results are shown in Table 5.The C and H contents of the sludge were lower than those of the cotton straw or corn stover, while the contents of O, N, and S were higher than those of the cotton straw or corn stover.Generally, greater amounts of C correlate with greater heat generation, while high H content makes ignition and burning easier.However, higher O contents can inhibit combustion 31 .Therefore, cotton straw or corn stover has a higher heat generation during combustion than sludge, and ignition and combustion are easier than sludge.The industrial analysis showed that the sludge moisture and ash contents were higher than those of cotton straw and corn stover, but the volatile fraction and fixed carbon ratios were lower.Lower moisture and ash contents reduce energy consumption 32,33 , thereby improving the thermal efficiency of combustion; meanwhile, higher volatile matter and fixed carbon ratios, generate more heat during combustion, improving the utilisation rate of combustion.This result suggests that cotton straw and corn stover require less energy consumption during combustion and maintain higher thermal efficiency and heat generation than does sludge alone.

Microstructure analysis
The SEM images of the sludge, cotton straw, and corn stover before and after blending are shown in Fig. 4. As shown in Fig. 4a, the sludge consisted of irregularly sized particles with rough surfaces, complex lumpy structures, and pores of different sizes.As shown in Fig. 4b, cotton straw had a laminar void and a relatively loose structure.
As shown in Fig. 4c, corn stover also had a lamellar structure, but with a denser outer surface.As shown in Fig. 4d,e, cotton straw and corn stover particles were attached to the surface of the sludge particles after blending.www.nature.com/scientificreports/

Thermogravimetric analysis
Relevant data show that when sludge and other substances are mixed and burned, the water content is reduced to 30-40% 34 , which is conducive to increasing the temperature of combustion, and the combustion is more stable 25 .So this study selected 60% sludge and 40% cotton straw for mixing combustion, thermogravimetric experiment results are shown in Fig. 5a.The weight loss stages of the sludge were the same as those of cotton straw and corn stover across all three stages 35 ; however, the maximum rate of weight loss and final weight loss rate in the three stages of cotton straw and corn stover was greater than that of the sludge, indicating that the combustion of cotton straw and corn stover was more complete, and the burning rate was higher than that of sludge alone 36 .
Figure 5b shows the thermogravimetric curves of the sludges mixed with cotton straw or corn stover.The TG-DTG of both sets of mixed samples showed three phases, each of which occurred at approximately the same temperature interval as in the case of sludge burning alone, indicating that mixing sludge burning with these two types of agricultural waste did not alter the weight loss phase.The blended combustion increased the weight loss rate across the three stages, but the weight loss rate of the 60% sludge + 40% cotton straw was greater 37 than that of the 60% sludge + 40% corn stover ratio, and the blended combustion left less residue, suggesting that the addition of the agricultural waste effectively improved the sludge combustion rate, made the sludge burn more fully, and resulted in a higher burnout rate 38 .

Non-isothermal kinetic fitting and activation energy study
The results of non-isothermal kinetic fitting are shown in Fig. 6 and the results of the activation energy calculations are shown in Table 6.The average activation energy of sludge alone was 116.65 kJ/mol, and the addition of cotton straw or corn stover reduced the activation energy of sludge by 12.74 kJ/mol for the 60% sludge + 40% cotton straw mixture and 5.58 kJ/mol for the 60% sludge + 40% corn stover mixture.Therefore, the addition of cotton straw or corn stover promoted sludge combustion 39 , though the cotton straw mix had a stronger positive effect.Taken together, these results suggest that the mixture of 60% sludge + 40% cotton straw produced the lowest reaction activation energy of sludge combustion, and thus exhibited better combustion performance 40,41 .(e) 60% sludge + 40% cotton straw; (f) 60% sludge + 40% cotton straw The six groups of hearth temperature cloud maps were ultimately similar in distribution, and the temperature fields were all relatively stable, indicating that the addition of cotton straw did not affect the flame combustion pattern in the hearth.With an increase in the cotton straw blending ratio, however, the furnace chamber temperature gradually increased.The highest temperature of sludge combustion alone was 1485.60℃, while the maximum temperature was 1564.12 °C after adding 50% cotton straw, likely because the addition of cotton straw increased the fixed carbon content and reduced the moisture and ash contents of the sludge, resulting in a higher combustion temperature in the furnace.

Temperature cloud of sludge mixed with corn stover combustion
The boiler temperature variations of the sludge and corn stover combustion at different blending ratios are shown in Fig. 8.The simulation results for the combustion of the sludge and corn stover blends appear similar to those for the sludge and cotton straw blends, with the furnace chamber temperature increasing with the increase in corn stover content.When the proportion of corn stover was 50% sludge to 50% corn stover, the highest temperature, 1547.92℃, was reached, likely because the addition of corn stover reduced the moisture and ash contents of the sludge and increased the fixed carbon content, thereby increasing the combustion temperature of the furnace.

Pollutant emissions from co-combustion of sludge and cotton straw
Figure 9 shows the temperature and pollutant emission profiles of sludge and cotton straw combustion under different blending ratios.Based on the temperature curves, the overall trend of the six sets of curves was similar, with the temperature first increasing and then slowly decreasing as the height of the hearth increases 42 .The high-temperature region of furnace combustion occurred in the main combustion region, which is consistent with actual boiler operation 43 .As the proportion of cotton straw increased, the combustion temperature in the furnace chamber also gradually increased.
The CO mass fraction curve with hearth height first increased and then decreased.CO mass fraction increased with the increase of cotton straw blending ratio, the sludge combustion alone for 8.42 × 10 -5 , blended with 50% cotton straw for 6.47 × 10 -4 , indicating that greater levels of cotton straw during combustion increased the production of CO.This is because the temperature of the chamber increases more rapidly for a larger proportion of cotton straw; thus, the mixture burns faster and the surrounding oxygen is consumed at a faster rate than the incoming oxygen, resulting in insufficient local burning and an increase in the mass fraction of CO 44 .SO 2 production appeared to increase and then decrease with the increase in furnace height; in the main combustion zone, the sludge combustion of the SO 2 mass fraction was the largest, 2.10 × 10 -3 .The SO 2 mass fraction peaks reduced significantly with a larger fraction of cotton straw; specifically, blending with 50% cotton straw resulted in the lowest production of SO 2 .The formation of SO 2 is closely related to the sulfur content of the material.The content of elemental S in sludge was higher than that of cotton straw, therefore, with an increase in the cotton straw blending ratio, the content of elemental S decreased, and the emission of SO 2 decreased.
The NO concentration increased and then decreased along the hearth height, with a slight increase near the flue gas outlet.The NO concentration was mainly concentrated near the main combustion zone, which had the highest temperature and produced large amounts of fuel-and thermal-type NO x 45 .Lower temperatures in the lower and upper parts of the boiler reduce thermal NO x production.There was a slight increase in the NO concentration near the furnace exit, likely due to the increase in NO emissions resulting from poorer combustion performance.As the percentage of cotton straw increased, the concentration of NO decreased gradually, while the highest value of NO concentration for sludge combustion alone was 794.42 mg/m 3 , and 586.41 mg/m 3 after blending with 50% cotton straw, which resulted in a decrease of 208.01 mg/m 3 .10 shows the temperature and pollutant emission profiles of sludge and corn stover combustion for different blending ratios.With an increase in the height of the furnace chamber, the temperature first rose and then slowly decreased, and the temperature inside the furnace chamber gradually increased as the proportion of corn stover increased in the blend.
The CO mass-fraction profile peaked in the main combustion zone and approached zero near the slag and smoke outlets.The maximum CO mass fraction was 4.1 × 10 -4 for the with 50% corn stover blend.The higher the corn stover proportion in the blend, the higher the resulting CO mass fraction.
The SO 2 trend was similar to that of the boiler combustion temperature, with high SO 2 content in the hightemperature zone and low SO 2 content in the lower part of the furnace and exhaust port.As the proportion of corn stover increased, the SO 2 in the furnace chamber gradually decreased.The mass fraction of SO 2 was 1.68 × 10 -3 when mixed with 50% corn stover.
The NO concentration curve first increased then decreased, with the curve flattening at approximately 30 ~ 50 m furnace height followed by a slight increase at the flue gas outlet.The lowest NO concentration, 632.61 mg/m 3 , was produced from the 50% corn stover blend, and the NO concentration at the furnace exit also decreased with increasing corn stover blending ratio.This is consistent with the findings of Hongpeng Liu 46    www.nature.com/scientificreports/Comparative analysis of sludge blended with different ratios of cotton straw and corn stover for combustion A comparison of the simulation results for the combustion of sludge blended with cotton straw or corn stover is shown in Fig. 11. Figure 11a shows that, with an increase in the proportion of cotton straw or corn stover, the combustion temperature in the furnace chamber gradually increased, with the greatest increase coming from the cotton straw mix.For the 50% cotton straw or corn stover sludge mixes, the temperatures increased by 226.24 °C and 173.65 °C, respectively.The combustion of sludge mixed with either cotton straw or corn stover resulted in increased CO emissions.When the proportion of cotton straw or corn stover in the sludge blend was less than 30%, the amount of CO produced by the cotton straw blend was lower, whereas when the mixing amount of cotton straw or corn stover was 30%-50%, the amount of CO produced by the mixed combustion of sludge and corn stover was smaller.
Overall, the combustion of sludge mixed with cotton straw or corn stover reduced SO 2 and NO emissions, which is due to the fact that SO 2 and NO emissions are mainly determined by the sulphur and nitrogen content of the substance 47 .The elemental analysis shows that, under the same blending ratio, lower SO 2 emissions from combustion of sludge mixed with cotton straw occurred due to lower elemental S in cotton straw.Moreover, NO is mainly composed of fuel and thermal types 48 , of which fuel types account for 60%-80% of all NO, and thermal types account for about 20%.Fuel-type NO content is mainly determined by the N-element content of the burning material.Mao Ya 49 et al. (2017) found that the NO burned by cotton straw was lower than that of corn stover.Thus, given that cotton straw had only half the N content of corn stover 50 , the NO produced by blending cotton straw burning was lower than that of corn stover.

Conclusions
1. Blending sludge with cotton straw or corn stover for combustion increased the rate of weight loss and combustion exhaustion and decreased the activation energy of the reaction.When a ratio of 60% of sludge to 40% of cotton straw was burned, the activation energy decreased by 12.74 kJ/mol, while that with corn stover decreased by 5.58 kJ/mol.In summary, the addition of cotton straw or corn stover improved combustion performance compared to that of sludge alone.2. At the same blending ratio, the combustion temperatures of sludge and cotton straw were higher than those of sludge and corn stover.Specifically, the furnace temperature increased by 226.24 and 173.65℃ when the percentages of cotton straw and corn stover, respectively, were 50%.3. The CO content in the boiler increased with increasing cotton straw or corn stover blending ratios.When the ratio of cotton straw or corn stover was less than 30%, the CO content of the sludge and cotton straw blending and combustion was smaller.When the ratio of cotton straw to stover was 30%-50%, the CO content of the sludge and corn stover blending and combustion was smaller.4. The SO 2 and NO contents in the boiler gradually decreased with an increase in the blending ratio of cotton straw or corn stover.Because the S and N contents of the cotton straw were lower than those of the corn stover, the SO 2 and NO contents produced by the mixed burning of sludge and cotton straw were lower than those of sludge and corn stover at the same ratio.
Experimental studies and finite element simulations have shown that mixing sludge and cotton straw for combustion can be more efficient in reducing the activation energy required for combustion, increasing the temperature of blended combustion, and reducing the emission of pollutants from blended combustion, compared to blending with corn stover.Therefore, a more in-depth study on sludge and cotton-straw-blended combustion should be carried out to further optimise the blending method and combustion conditions to improve the performance of sludge combustion in accordance with the Dual Carbon Strategy goals.

Figure 1 .
Figure 1.Conceptualization of municipal Sludge Combustion in Xinjiang.

Figure 3 .
Figure 3. Modelling and meshing of a four-corner, cut-circle combustion furnace.

Figure 5 .
Figure 5. Thermogravimetric curves.(a) Thermogravimetric curves of sludge, cotton straw, and corn stover burned individually; (b) thermogravimetric curve of combustion of sludge blended with cotton straw and corn stover.

Figure 6 .
Figure 6.Kinetic fitting of sludge, cotton straw and corn stover combustion alone and blended combustion.(a) The first stage; (b) The second stage; (c) The third stage.
et al. (2021) that the incorporation of corn stover reduces NO and SO 2 emissions.

Figure 9 .
Figure 9. Temperature and pollutant emission distribution of sludge and cotton straw combustion at different blending ratios.

Figure 10 .
Figure 10.Temperature and pollutant emission distribution of sludge and corn stover combustion at different blending ratios.

Figure 11 .
Figure 11.Comparison of combustion simulation results of sludge blended with cotton straw or corn stover.(a) Temperature; (b) CO mass fractions; (c) of mass fractions of SO2; (d) NO concentrations.

Table 1 .
Instrument type and model.

Table 3 .
Operational parameters of the 330MW quad-cut circle combustion furnace setup.

Table 4 .
Simulated combustion feed ratios of sludge, cotton straw, and corn stover for a 330 MW quadcircular combustion furnace.

Table 6 .
Elemental analyses, industrial analyses, and calorific values of sludge, cotton straw, and corn stover.